Which of the following is NOT a characteristic of supramolecular chemistry?
a) Weak intermolecular forces
b) Dynamic nature
c) High covalent bond strength
d) Reversible interactions
Answer: Answer: c) High covalent bond strength
What type of interactions are involved in supramolecular chemistry?
a) Covalent bonds
b) Ionic bonds
c) Hydrogen bonds
d) Metallic bonds
Answer: Answer: c) Hydrogen bonds
Which property of supramolecular assemblies makes them reversible?
a) Weak intermolecular forces
b) Covalent bonding
c) Electrostatic interactions
d) High melting point
Answer: Answer: a) Weak intermolecular forces
Which of the following is an example of supramolecular self-assembly?
a) Polymerization
b) Crystallization
c) Hydrolysis
d) Oxidation
Answer: Answer: b) Crystallization
Which supramolecular phenomenon involves the binding of a host molecule to a guest molecule?
a) Templating
b) Encapsulation
c) Host-guest complexation
d) Supramolecular polymerization
Answer: Answer: c) Host-guest complexation
What is the driving force behind the formation of host-guest complexes?
a) Entropy increase
b) Entropy decrease
c) Energy increase
d) Energy decrease
Answer: Answer: a) Entropy increase
Which of the following techniques can be used to characterize supramolecular assemblies?
a) NMR spectroscopy
b) Mass spectrometry
c) X-ray crystallography
d) All of the above
Answer: Answer: d) All of the above
What is the primary driving force for supramolecular polymerization?
a) Covalent bonding
b) Electrostatic interactions
c) Hydrogen bonding
d) Van der Waals forces
Answer: Answer: c) Hydrogen bonding
Which of the following is an example of a supramolecular assembly?
a) Protein
b) Polymer
c) Metal alloy
d) Glass
Answer: Answer: a) Protein
What is the role of template molecules in templating reactions?
a) They act as catalysts
b) They provide structural support
c) They increase reaction rates
d) They inhibit the reaction
Answer: Answer: b) They provide structural support
What is the primary driving force for the formation of coordination complexes?
a) Covalent bonding
b) Hydrogen bonding
c) Metallic bonding
d) Coordination bonds
Answer: Answer: d) Coordination bonds
Which of the following is a supramolecular motif characterized by a cyclic arrangement of molecules?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
Which supramolecular assembly is characterized by a spherical structure with an outer shell of polar groups and an inner cavity?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: b) Vesicle
What is the role of cucurbiturils in supramolecular chemistry?
a) They act as catalysts
b) They form host-guest complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form host-guest complexes
Which of the following is an example of a mechanically interlocked molecule?
a) DNA
b) Protein
c) Rotaxane
d) Supramolecular polymer
Answer: Answer: c) Rotaxane
What is the primary driving force for the formation of inclusion complexes?
a) Covalent bonding
b) Hydrogen bonding
c) Van der Waals forces
d) Electrostatic interactions
Answer: Answer: c) Van der Waals forces
Which supramolecular assembly is characterized by a core-shell structure formed by amphiphilic molecules?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: a) Micelle
What is the role of metal ions in coordination chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which of the following is an example of a molecular recognition process in supramolecular chemistry?
a) Enzymatic catalysis
b) Electrochemical reactions
c) Radical polymerization
d) Metal-catalyzed reactions
Answer: Answer: a) Enzymatic catalysis
Which of the following techniques is used to study the supramolecular interactions between biomolecules?
a) X-ray crystallography
b) Nuclear magnetic resonance (NMR) spectroscopy
c) Mass spectrometry
d) Scanning electron microscopy (SEM)
Answer: Answer: b) Nuclear magnetic resonance (NMR) spectroscopy
What is the role of cyclodextrins in supramolecular chemistry?
a) They act as catalysts
b) They form inclusion complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form inclusion complexes
Which of the following is an example of a supramolecular gel?
a) Jello
b) Toothpaste
c) Rubber
d) Paint
Answer: Answer: b) Toothpaste
What is the primary driving force for the self-assembly of amphiphilic molecules?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Van der Waals forces
Answer: Answer: a) Hydrophobic effect
Which of the following is a supramolecular assembly composed of two or more interlocked macrocycles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the role of crown ethers in supramolecular chemistry?
a) They act as catalysts
b) They form host-guest complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form host-guest complexes
Which supramolecular assembly is characterized by the encapsulation of guest molecules within a hydrophobic core?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: a) Micelle
What is the primary driving force for the formation of hydrogen-bonded supramolecular assemblies?
a) Covalent bonding
b) Electrostatic interactions
c) Hydrogen bonding
d) Van der Waals forces
Answer: Answer: c) Hydrogen bonding
Which of the following is an example of a supramolecular catalyst?
a) Enzyme
b) Metal complex
c) Homogeneous catalyst
d) Heterogeneous catalyst
Answer: Answer: a) Enzyme
What is the role of zeolites in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: c) They provide structural support
Which of the following is an example of a supramolecular material?
a) Glass
b) Metal alloy
c) Rubber
d) Hydrogel
Answer: Answer: d) Hydrogel
What is the primary driving force for the formation of metal-organic frameworks (MOFs)?
a) Covalent bonding
b) Hydrogen bonding
c) Metallic bonding
d) Coordination bonds
Answer: Answer: d) Coordination bonds
Which of the following is a supramolecular assembly composed of a bilayer of amphiphilic molecules?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: b) Vesicle
What is the role of calixarenes in supramolecular chemistry?
a) They act as catalysts
b) They form inclusion complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form inclusion complexes
Which supramolecular assembly is characterized by a threaded structure formed by a macrocycle and an axle molecule?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: c) Rotaxane
What is the primary driving force for the self-assembly of DNA molecules?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Van der Waals forces
Answer: Answer: b) Electrostatic interactions
Which of the following is an example of a supramolecular sensor?
a) pH indicator
b) Thermometer
c) Voltmeter
d) Spectrophotometer
Answer: Answer: a) pH indicator
What is the role of cyclotriveratrylene (CTV) in supramolecular chemistry?
a) It acts as a catalyst
b) It forms host-guest complexes
c) It provides structural support
d) It enhances reaction rates
Answer: Answer: b) It forms host-guest complexes
Which supramolecular assembly is characterized by the entanglement of two or more macrocycles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the formation of charge-transfer complexes?
a) Covalent bonding
b) Hydrogen bonding
c) Charge transfer
d) Van der Waals forces
Answer: Answer: c) Charge transfer
Which of the following is an example of a supramolecular catalyst?
a) Enzyme
b) Metal complex
c) Homogeneous catalyst
d) Heterogeneous catalyst
Answer: Answer: c) Homogeneous catalyst
What is the role of metal-organic cages in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of a linear polymer chain within itself?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: c) Rotaxane
What is the primary driving force for the self-assembly of peptide molecules?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Van der Waals forces
Answer: Answer: b) Electrostatic interactions
Which of the following is an example of a supramolecular drug delivery system?
a) Pill
b) Syringe
c) Inhaler
d) Bandage
Answer: Answer: c) Inhaler
What is the role of metal-organic polyhedra in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple linear polymer chains?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the formation of π-π stacking interactions?
a) Covalent bonding
b) Hydrogen bonding
c) π-electron interactions
d) Van der Waals forces
Answer: Answer: c) π-electron interactions
Which of the following is an example of a supramolecular switch?
a) Light bulb
b) Doorbell
c) Thermostat
d) pH indicator
Answer: Answer: d) pH indicator
What is the role of metal-organic rotors in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple vesicles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the self-assembly of peptide nucleic acid (PNA) molecules?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Van der Waals forces
Answer: Answer: b) Electrostatic interactions
Which of the following is an example of a supramolecular biosensor?
a) Glucose meter
b) Blood pressure monitor
c) ECG machine
d) X-ray machine
Answer: Answer: a) Glucose meter
What is the role of metal-organic frameworks (MOFs) in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple micelles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the formation of chiral supramolecular assemblies?
a) Covalent bonding
b) Hydrogen bonding
c) Electrostatic interactions
d) Chiral induction
Answer: Answer: d) Chiral induction
Which of the following is an example of a supramolecular photoswitch?
a) Light bulb
b) Doorbell
c) Thermometer
d) Azobenzene
Answer: Answer: d) Azobenzene
What is the role of metal-organic polymeric networks in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of a linear polymer chain and a cyclic molecule?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: c) Rotaxane
What is the primary driving force for the self-assembly of peptide amphiphiles?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Van der Waals forces
Answer: Answer: a) Hydrophobic effect
Which of the following is an example of a supramolecular imaging agent?
a) MRI contrast agent
b) X-ray contrast agent
c) PET tracer
d) Ultrasound contrast agent
Answer: Answer: a) MRI contrast agent
What is the role of metallo-supramolecular complexes in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple rotaxanes?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the formation of supramolecular liquid crystals?
a) Covalent bonding
b) Hydrogen bonding
c) π-electron interactions
d) Van der Waals forces
Answer: Answer: d) Van der Waals forces
Which of the following is an example of a supramolecular drug carrier?
a) Pill
b) Syringe
c) Inhaler
d) Liposome
Answer: Answer: d) Liposome
What is the role of metal-organic cages in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple vesicles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
What is the primary driving force for the self-assembly of metallo-supramolecular polymers?
a) Hydrophobic effect
b) Electrostatic interactions
c) Covalent bonding
d) Coordination bonds
Answer: Answer: d) Coordination bonds
Which of the following is an example of a supramolecular sensor for metal ions?
a) pH indicator
b) Glucose meter
c) Thermometer
d) Ion-selective electrode
Answer: Answer: d) Ion-selective electrode
What is the role of metal-organic frameworks (MOFs) in supramolecular chemistry?
a) They act as catalysts
b) They form coordination complexes
c) They provide structural support
d) They enhance reaction rates
Answer: Answer: b) They form coordination complexes
Which supramolecular assembly is characterized by the entanglement of multiple micelles?
a) Micelle
b) Vesicle
c) Rotaxane
d) Catenane
Answer: Answer: d) Catenane
